The influence of Nb and Zr on glass-formation ability in the ternary Fe-Nb-B and Fe-Zr-B and quaternary Fe-(Nb,Zr)-B alloy systems

被引:28
|
作者
Yao, J. H. [1 ]
Yang, H. [1 ]
Zhang, J. [1 ]
Wang, J. Q. [1 ]
Li, Y. [2 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117576, Singapore
关键词
D O I
10.1557/JMR.2008.0055
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Glass-forming ability (GFA) in relation to microstructure evolution in the ternary Fe-Nb-B and Fe-Zr-B and quaternary Fe-(Nb,Zr)-B systems was systematically studied in a three-dimensional composition space. Through navigating, it was revealed that alloys with the optimum glass-forming ability (GFA) are coupled with composition regions surrounded by competing crystalline phases. Alloys Fe71Nb6B23, Fe77Zr4B19, and Fe-71(Nb0.8Zr0.2)(6)B-23 were illustrated to be the best glass formers in the ternary Fe-Nb-B and Fe-Zr-B systems and the quaternary Fe-(Nb,Zr)-B system, respectively, with a critical size for amorphous formation up to 2 mm. They were compared with the theoretical predictions on the basis of an efficient dense-packing model, and good agreements were obtained.
引用
收藏
页码:392 / 401
页数:10
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