N-Vinyl Ferrocenophane Pyrrole: Synthesis and Physical and Chemical Properties

被引：15
|
作者：
Galangau, Olivier [1 ]
Dumas-Verdes, Cecile [1 ]
Schmidt, Elena Yu [2 ]
Trofimov, Boris A. [2 ]
Clavier, Gilles [1 ]
机构：
[1] CNRS, ENS Cachan, PPSM, F-94230 Cachan, France
[2] Russian Acad Sci, Siberian Branch, AE Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 23期
关键词：
HIGHLY SUBSTITUTED PYRROLES; MULTICOMPONENT REACTIONS; BRIDGED FERROCENES; BODIPY DYES; BROMOFERROCENE; CHEMISTRY;
D O I：
10.1021/om200839b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new synthesis of [3]ferrocenophan-1-one has been developed, and a Trofimov reaction has been applied to its ketoxime. The novel subsequent N-vinyl pyrrole ferrocenophane displays reversible electrochemical behavior centered on the ferrocene, without any participation of the pyrrole. Unexpected byproduct was also isolated, in which the a-pyrrolic position is methylated.
引用
收藏
页码：6476 / 6481
页数：6
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