Experimental and computational investigations of the properties of fluorinated single-walled carbon nanotubes

被引：62
|
作者：
Bettinger, HF [1 ]
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Organ Chem 2, D-44780 Bochum, Germany
来源：
CHEMPHYSCHEM | 2003年 / 4卷 / 12期
关键词：
density functional calculations; fluorine; nanotubes; solubility; thermochemistry;
D O I：
10.1002/cphc.200300854
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Fluorination of single-walled carbon nanotubes by reaction with elemental fluorine at elevated temperatures provides fluorinated single-walled carbon nonotubes (F-SWNT), which have the highest degree of functionalization (up to F/C= 1/2) of any derivatized carbon-nanotube material reported to dote. Also, F-SWNTs have received more scrutiny than any other functionalized carbon nanotubes. This Minireview covers experimental and computational investigations of F-SWNTs with a focus on the nature and the strength of the C-F linkage.
引用
收藏
页码：1283 / 1289
页数：7
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