Preparation of nano-sized nickel as anode catalyst for direct urea and urine fuel cells

被引:147
|
作者
Lan, Rong [1 ]
Tao, Shanwen [1 ]
机构
[1] Univ Strathclyde, Dept Chem & Proc Engn, Glasgow G1 1XJ, Lanark, Scotland
基金
英国工程与自然科学研究理事会;
关键词
Fuel cell; Urea; Urine; Nano-materials; Nickel; NANOPARTICLES;
D O I
10.1016/j.jpowsour.2011.02.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano-sized nickel with primary particle size of 2-3 nm has been successfully prepared for use as efficient anode catalysts in urea and urine fuel cells. XRD. SEM and TEM were used for characterisation of nanosized nickel. Based on the previous communication, the performance of urea and urine fuel cells has been further improved when the relative humidity at the cathode was 100%. A maximum power density of 14.2 mW cm(-2) was achieved when 1 M urea was used as fuel, humidified air as oxidant. The performance of urine fuel cells operating above room temperature was also reported for the first time and a power density of 4.23 mW cm(-2) was achieved at 60 degrees C indicating potential application in urea-rich waste water treatment. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:5021 / 5026
页数:6
相关论文
共 50 条
  • [1] Preparation of Ni@MWCNTs Anode Catalyst and Its Application in Direct Urea (Urine) Fuel Cell
    Chen Xiaofei
    Liu Zhaoyang
    Lei Yang
    Fan Baoan
    Guo Fen
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2018, 39 (03): : 537 - 544
  • [2] Synthesis of Dendritic Nano-Sized Nickel for use as Anode Material in an Alkaline Membrane Fuel Cell
    Ewing, S. J.
    Lan, R.
    Xu, X. X.
    Tao, S. W.
    [J]. FUEL CELLS, 2010, 10 (01) : 72 - 76
  • [3] Direct Urea Fuel Cells Based on CuNi Plated Cloth as Anode Catalyst
    Kaneto, Keiichi
    Nishikawa, Mao
    Uto, Sadahito
    Osawa, Toshiyuki
    [J]. CHEMISTRY LETTERS, 2018, 47 (10) : 1285 - 1287
  • [4] Nano-sized nickel catalyst for deep hydrogenation of lignin monomers and first-principles insight into the catalyst preparation
    Qi, Shi-Chao
    Zhang, Lu
    Einaga, Hisahiro
    Kudo, Shinji
    Norinaga, Koyo
    Hayashi, Jun-ichiro
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (08) : 3948 - 3965
  • [5] Preparation of nano-sized nickel metal particles by microwave irradiation
    Wada, Y
    Kuramoto, H
    Sakata, T
    Mori, H
    Sumida, T
    Kitamura, T
    Yanagida, S
    [J]. CHEMISTRY LETTERS, 1999, (07) : 607 - 608
  • [6] Preparation of porous, nano-sized urea-formaldehyde polymer powder
    Lee, Chul-Tae
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (03) : 919 - 925
  • [7] A mild and recyclable nano-sized nickel catalyst for the Stille reaction in water
    Wu, Lei
    Zhang, Xiao
    Tao, Zhimin
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (04) : 707 - 710
  • [8] Fast preparation of nano-sized nickel particles under microwave irradiation without using catalyst for nucleation
    Tsuji, M
    Hashimoto, M
    Tsuji, T
    [J]. CHEMISTRY LETTERS, 2002, (12) : 1232 - 1233
  • [9] Pronounced synergetic effect of the nano-sized PtSnNi/C catalyst for ethanol oxidation in direct ethanol fuel cell
    Beyhan, Seden
    Leger, Jean-Michel
    Kadirgan, Figen
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 130 : 305 - 313
  • [10] Direct urea fuel cells based on CuNi-plated polymer cloth as a anode catalyst
    Kaneto, Keiichi
    Nishikawa, Mao
    Uto, Sadahito
    [J]. MRS COMMUNICATIONS, 2019, 9 (01) : 88 - 91