Molecular compasses and gyroscopes: Engineering molecular crystals with fast internal rotation

被引：56

作者：

Khuong, TAV ^{[1
]}

Zepeda, G ^{[1
]}

Ruiz, R ^{[1
]}

Khan, SI ^{[1
]}

Garcia-Garibay, MA ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

CRYSTAL GROWTH & DESIGN | 2004年 / 4卷 / 01期

关键词：

D O I：

10.1021/cg034144b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals of 1,4-bis[3,3,3-tri(3,4-ditertbutyl)phenylpropynyl] benzene 1c may be viewed as a collection of molecular gyroscopes having a central p-diethynylphenylene as a rotary element encased by two bulky triarylmethyl groups. Single-crystal X-ray analysis, C-13 CPMAS NMR, and H-2 NMR quadrupolar-echo line-shape analysis revealed a lattice of molecules with phenylene groups experiencing rotary motion in the gigahertz regime near ambient temperature.

引用

页码：15 / 18

页数：4

共 50 条

[1] Molecular gyroscopes and compasses: Engineering motion into organic crystalline materials
O'Brien, Zachary J.
Garcia-Garibay, Miguel A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
[2] Molecular compasses and gyroscopes: Rotary dynamics in the crystalline solid state
Garcia-Garibay, Miguel A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3004 - U3004
[3] Molecular compasses and gyroscopes with polar rotors: Synthesis and characterization of crystalline forms
Garcia-Garibay, M.A. (mgg@chem.ucla.edu), 1600, American Chemical Society (125):
[4] Molecular compasses and gyroscopes with polar rotors:: Synthesis and characterization of crystalline forms
Dominguez, Z
Khuong, TAV
Dang, H
Sanrame, CN
Nuñez, JE
Garcia-Garibay, MA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (29) : 8827 - 8837
[5] INFLUENCE OF INTERNAL ROTATION OF MOLECULES ON THERMAL CONDUCTIVITY OF MOLECULAR CRYSTALS
MOGILEVS.BM
SURIN, VG
SOVIET PHYSICS SOLID STATE,USSR, 1971, 12 (11): : 2522 - +
[6] Engineering molecular crystals
Wuest, JD
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3181 - U3183
[7] Molecular gyroscopes
不详
NATURE MATERIALS, 2004, 3 (11) : 748 - 748
[8] Engineering Crystal Packing and Internal Dynamics in Molecular Gyroscopes by Refining their Components. Fast Exchange of a Phenylene Rotator by 2H NMR
Garcia-Garibay, Miguel A.
Godinez, Carlos E.
CRYSTAL GROWTH & DESIGN, 2009, 9 (07) : 3124 - 3128
[9] A MOLECULAR ORBITAL STUDY OF INTERNAL ROTATION
GORDON, MS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (12) : 3122 - &
[10] Methyl and ammonia rotation in molecular crystals
Schiebel, P.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2000, 56 : S126 - S126

← 1 2 3 4 5 →