Experimental study of hydrogen production process with aluminum and water

被引:35
|
作者
Bolt, Andre [1 ]
Dincer, Ibrahim [1 ]
Agelin-Chaab, Martin [1 ]
机构
[1] Ontario Tech Univ, Clean Energy Res Lab CERL, Fac Engn & Appl Sci, 2000 Simcoe St North, Oshawa, ON L1H 7K4, Canada
关键词
Hydrogen production; Aluminum; Water; Sodium hydroxide; Efficiency; GENERATION PERFORMANCE; WASTE ALUMINUM; HYDROLYSIS; CHEMISTRY; ALLOYS;
D O I
10.1016/j.ijhydene.2020.03.160
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study reported a novel hydrogen production experimental set up, which utilizes the chemical reaction between aluminum and water to produce hydrogen. The developed experimental setup had an aluminum powder spraying subsystem integrated within the overall setup. The effectiveness of this hydrogen production experimental set up was improved using 149-mu m aluminum powder, and nitrogen gas as the medium to facilitate the spraying of the aluminum powder. Furthermore, the study utilized sodium hydroxide as the reaction promoter. The various experimental conditions implemented during the testing process included changes in the water temperature and system inputs. The criteria used to evaluate the system performance were the hydrogen yield and hydrogen production rate. The tap water was able to achieve a full hydrogen yield due to its composition, however, the 50% increase in NaOH mass trial was able to achieve a higher yield of 97.15% and 95.44% for the 3g and 6g aluminum sample test respectively. Furthermore, seawater was found to achieve a yield of 58.8%, which can be considered a viable option for future testing. Furthermore, seawater's abundance also adds to its viability for future testing. Also, the study results showed that an increase in reaction temperature best facilitates a chemical reaction taking place. This was evident during the staring temperature of the water test for the 6g aluminum samples. For instance, the maximum hydrogen production rate for the 70 degrees C was 35.04 mL/s, while the smallest peak for hydrogen production rate was observed using the 40 degrees C as the starting temperature. The 40 degrees C test produced a maximum hydrogen production rate value of 27.99 mL/s. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:14232 / 14244
页数:13
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