Clean and efficient synthesis of 3-aminoindolizines in one-pot using recyclable CuCN/[bmim]PF6 system

被引：4

作者：

Mohammod, Muqeed ^{[1
]}

Guguloth, Veeranna ^{[2
]}

Vasam, Chandra Sekhar ^{[3
]}

Thirukovela, Narasimha Swamy ^{[1
]}

机构：

[1] Chaitanya Deemed Univ, Dept Chem, Hanamkonda, Telangana, India

[2] Kakatiya Univ, Dept Chem, Hanamkonda, India

[3] Telangana Univ, Dept Pharmaceut Chem, Nizamabad, India

来源：

SYNTHETIC COMMUNICATIONS | 2022年 / 52卷 / 9-10期

关键词：

3-Aminoindolizines; CuCN; bmim]PF6; intramolecular cyclization; Mannich-Grignard addition; one-pot synthesis; TEMPERATURE IONIC LIQUIDS; MULTICOMPONENT REACTIONS; ASYMMETRIC HYDROGENATION; INDOLIZINE DERIVATIVES; ARYLBORONIC ACIDS; LAMELLARIN-D; CATALYST; WATER; SOLVENTS; CYCLOISOMERIZATION;

D O I：

10.1080/00397911.2022.2081811

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we first time developed a simple, readily available, clean and efficient CuCN/[bmim][PF6] system for the one-pot synthesis of 3-aminoindolizines using commercially available starting materials which included pyridine-2-carbaldehyde, secondary amines, and terminal alkynes. As well, the CuCN/[bmim][PF6] system was reused six times without any appreciable change in its activity.

引用

页码：1254 / 1267

页数：14

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