Electron-transfer induced mesomorphism in the ferrocene-ferrocenium redox system: First ferrocenium-containing thermotropic liquid crystal

被引:64
|
作者
Deschenaux, R [1 ]
Schweissguth, M [1 ]
Levelut, AM [1 ]
机构
[1] UNIV PARIS 11,PHYS SOLIDES LAB,F-91405 ORSAY,FRANCE
关键词
D O I
10.1039/cc9960001275
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemical oxidation (silver tosylate, acetone, room temperature) of a non-mesomorphic persubstituted ferrocene derivative leads to the corresponding ferrocenium species which exhibits a smectic A phase (polarized optical microscopy, differential scanning calorimetry, X-ray diffraction).
引用
收藏
页码:1275 / 1276
页数:2
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