Chemical potential, Gibbs-Duhem equation and quantum gases

被引:2
|
作者
Lee, M. Howard [1 ]
机构
[1] Univ Georgia, Dept Phys & Astron, Athens, GA 30602 USA
来源
关键词
Gibbs-Duhem equation; chemical potential; compressible and non compressible ideal gases; the third law; FREE FERMI GAS; STATISTICAL-MECHANICS; 2; DIMENSIONS; IDEAL-GASES; FLUCTUATIONS; TEMPERATURES;
D O I
10.1142/S0217979217501041
中图分类号
O59 [应用物理学];
学科分类号
摘要
Thermodynamic relations like the Gibbs-Duhem are valid from the lowest to the highest temperatures. But they cannot by themselves provide any specific temperature behavior of thermodynamic functions like the chemical potential. In this work, we show that if some general conditions are attached to the Gibbs-Duhem equation, it is possible to obtain the low temperature form of the chemical potential for the ideal Fermi and Bose gases very directly.
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页数:8
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