Tetrakis(μ-2-nitrobenzoato-κ2O:O′)bis[aqua-copper(II)] ethanol disolvate

被引：5
|
作者：
Moncol, Jan
Kavalirova, Jana
Lis, Tadeusz
Valigura, Dusan
机构：
[1] Slovak Tech Univ Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
CRYSTAL-STRUCTURE; COMPLEXES; FORMS;
D O I：
10.1107/S1600536806045296
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Cu-2(C7H4NO4)(4)(H2O)(2)](.)2C(2)H(6)O, forms a dimer of the paddle-wheel type located on a crystallographic inversion center. The two Cu2+ cations [Cu (.) (.) (.) Cu = 2.6543 (10) angstrom] are connected by four 2-nitrobenzoate ligands. The apical positions of the square-pyramidal copper coordination polyhedra are occupied by the water O atoms. The two ethanol solvent molecules are linked to complex molecules via O - H (.) (.) (.) O hydrogen bonds, which create one-dimensional chains of R-2(3)(13) and R-4(4)(12) rings. A pi-pi stacking interaction is observed between symmetry-related benzene rings of the 2-nitrobenzoate anions.
引用
收藏
页码：M3217 / M3219
页数：3
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