Organotin(IV) complexes of aromatic acid hydrazides: Preparation and spectroscopic studies

被引：0
|
作者：
Baul, SB [1 ]
Baul, TSB
Rivarola, E
机构：
[1] NE Hill Univ, Reg Sophisticated Instrumentat Ctr, Chem Lab, Shillong 793003, Meghalaya, India
[2] Univ Palermo, Dipartimento Chim Inorgan, I-90123 Palermo, Italy
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1999年 / 29卷 / 02期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The ability of aromatic acid hydrazides, RCONHNH2 to act as bidentate chelating agents towards diorganotin(IV) dichlorides has been investigated. The structure of the complexes were deduced from IR, NMR and Mossbauer spectroscopic techniques in combination with analytical data. The R2SnCl2. L complexes have octahedral geometry where the tin atom is chelated with one ligand (via carbonyl oxygen and hydrazinic nitrogen atoms), two chlorine atoms are in equatorial positions while the R groups are in the axial positions.
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页码：215 / 231
页数：17
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