Current status of adsorbent for metal ions with radiation grafting and crosslinking techniques

被引：104

作者：

Seko, N ^{[1
]}

Tamada, M ^{[1
]}

Yoshii, F ^{[1
]}

机构：

[1] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Takasaki, Gumma 3701292, Japan

来源：

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS | 2005年 / 236卷

关键词：

grafting; crosslinking; iminodiacetate; amidoxime; uranium; phosphoric; chitin-chitosan; paste-like;

D O I：

10.1016/j.nimb.2005.03.244

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

Removal of toxic metals from streaming water and ground water is important task to preserve environment. Radiation processing of grafting and crosslinking can synthesis adsorbent having high performances. Graft adsorbent can be synthesized by using the conventional polymer like polyethylene having variety shapes such as membrane, cloth, and fiber. Especially, the obtained fibrous adsorbent has 100 times higher rate of adsorption than that of commercialized resin. Fibrous adsorbent of iminodiacetate was applied to the removal of cadmium from the scallop waste. Furthermore, the amidoxime adsorbent is useful for recovery of rare metals such as uranium and vanadium in seawater. Novel fibrous adsorption for arsenic was synthesized by direct grafting of phosphoric monomer and following zirconium-loading. Crosslinked natural polymers like carboxymethyl chitin-chitosan in the paste-like state are applicable for the metal adsorbent. This adsorbent can be biodegraded after usage. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：21 / 29

页数：9

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