Non-metathesis ruthenium-catalyzed C-C bond formation

被引：771
|
作者：
Trost, BM [1 ]
Toste, FD [1 ]
Pinkerton, AB [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
CHEMICAL REVIEWS | 2001年 / 101卷 / 07期
关键词：
D O I：
10.1021/cr000666b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The non-metathesis ruthenium-catalyzed C-C bond formation was discussed. The reactions involving heteroatom additions to alkynes and allyl-ruthenium intermediates were elaborated. The oxa-ene reaction of electron-deficient aldehydes and alkenes was found to be catalyzed using cationic ruthenium-salen complex in nitromethane at 50°C. The cross-coupling of vinyl halides with olefins and alkyl Grignard reagents catalyzed by ruthenium complexes was also elaborated.
引用
收藏
页码：2067 / 2096
页数：30
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