Photopolymerization kinetics of multifunctional monomers

被引：806
|
作者：
Andrzejewska, E [1 ]
机构：
[1] Poznan Univ Technol, Fac Chem Technol, PL-60965 Poznan, Poland
来源：
PROGRESS IN POLYMER SCIENCE | 2001年 / 26卷 / 04期
关键词：
photopolymerization; kinetics; linear systems; crosslinking systems; modeling; propagation and termination rate coefficients; termination mechanism; effect of monomer structure and system composition; effect of temperature; effect of heteroatoms;
D O I：
10.1016/S0079-6700(01)00004-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This review article presents results of investigations concerning the kinetics of crosslinking photopolymerizations. The main emphasis is given to the propagation and termination rate coefficients and to the determination of the mechanism of the termination process. To emphasize the special features of the kinetics of the photocrosslinking process, a comparison with the kinetics of linear polymerizations has been made. Moreover, the paper describes the influence of various factors, both chemical as well as physical (e.g. monomer, structure, system composition, oxygen, temperature) on the chemistry of network formation. The effects of amino, ether and sulfide groups present in additives or introduced within monomer molecules are also discussed. (C) 2001 Elsevier Science Ltd. AU rights reserved.
引用
收藏
页码：605 / 665
页数：61
相关论文
共 50 条
  • [1] PHOTOPOLYMERIZATION OF MULTIFUNCTIONAL MONOMERS IN CONDENSED PHASE
    DECKER, C
    MOUSSA, K
    JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 34 (04) : 1603 - 1618
  • [2] SYNTHESIS AND PHOTOPOLYMERIZATION OF MULTIFUNCTIONAL PROPENYL ETHER MONOMERS
    CRIVELLO, JV
    KIM, WG
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1994, A31 (09): : 1105 - 1119
  • [3] PHOTOPOLYMERIZATION OF MULTIFUNCTIONAL MONOMERS .6. INFLUENCE OF PHOTOSTABILIZERS
    DECKER, C
    MOUSSA, K
    LEXUAN, H
    EUROPEAN POLYMER JOURNAL, 1991, 27 (11) : 1251 - 1260
  • [4] STUDY OF THE CATIONIC PHOTOPOLYMERIZATION OF MULTIFUNCTIONAL PROPENYL ETHER MONOMERS
    CRIVELLO, JV
    BRATSLAVSKY, SA
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1994, A31 (12): : 1927 - 1941
  • [5] A kinetic model for radical trapping in photopolymerization of multifunctional monomers
    Wen, M
    McCormick, AV
    MACROMOLECULES, 2000, 33 (25) : 9247 - 9254
  • [6] Kinetic model for radical trapping in photopolymerization of multifunctional monomers
    Wen, Mei
    McCormick, Alon V.
    2000, ACS, Washington, DC, United States (33)
  • [7] KINETICS OF PHOTOPOLYMERIZATIONS OF MULTIFUNCTIONAL MONOMERS
    KURDIKAR, DL
    PEPPAS, NA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 90 - PMSE
  • [8] Simulation of Models for Multifunctional Photopolymerization Kinetics
    Altun-Ciftcioglu, Gokcen A.
    Ersoy-Mericboyu, Aysegul
    Henderson, Clifford L.
    POLYMER ENGINEERING AND SCIENCE, 2014, 54 (08): : 1737 - 1746
  • [9] Radicals produced in the photopolymerization of multifunctional monomers, as probes of the polymeric structure
    Selli, E
    Oliva, C
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (02) : 497 - 507
  • [10] Photopolymerization of multifunctional monomers. VI. Influence of photostabilizers
    Photopolymerisation de monomeres multifonctionnels. VI. Influence de photostabilisants
    Decker, C., 1600, (27):
12345