Precise design and preparation of two 3D organic-inorganic perovskite ferroelectrics (1,5-diazabicyclo[3.2.2]nonane)RbX3 (X = Br, I)

被引：10

作者：

Han, Keke ^{[1
]}

Zhang, Mengxia ^{[1
]}

Wei, Zhenhong ^{[1
]}

Ye, Xing ^{[1
]}

Rao, Wenjun ^{[1
]}

Zhang, Haina ^{[1
]}

Cai, Hu ^{[1
]}

机构：

[1] Nanchang Univ, Sch Chem & Chem Engn, Nanchang 330031, Jiangxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 66期

关键词：

ROOM-TEMPERATURE FERROELECTRICITY; SOLAR-CELLS; BROMIDE; CRYSTALS; CATIONS; IODIDE; TIN;

D O I：

10.1039/d2cc02673b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Compared with the spherical molecule 1,4-diazoniabicyclo[2.2.2]-octane (2.2.2-dabco), 1,5-diazabicyclo[3.2.2]nonane (3.2.2-dabcn) bears a lower symmetry and larger size. As expected, reactions of 3.2.2-dabcn with rubidium halides gave two 3D molecular ferroelectrics [3.2.2-H(2)dabcn]RbX3 (X = Br for 1; X = I for 2) with T-c at 342 K (1) and 293 K (2).

引用

页码：9254 / 9257

页数：4

共 24 条

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Wei, Jing
Han, Keke
You, Xiuli
Zhang, Mengxia
Wei, Zhenhong
Zhang, Haina
Cai, Hu
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (71)
[2] Mechanical Properties of Single Crystal Organic-Inorganic Hybrid Perovskite MAPbX3 (MA = CH3NH3, X = Cl, Br, I)
Li, Jianyu
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Zhao, Zifan
Hu, Mingyu
Wang, Jun
Qian, Feng
Chong, Xiaoyu
Feng, Jing
COATINGS, 2023, 13 (05)
[3] Preparation and Properties of Films of Organic-Inorganic Perovskites MAPbX3 (MA = CH3NH3; X = Cl, Br, I) for Solar Cells: A Review
A. G. Belous
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P. V. Torchyniuk
Theoretical and Experimental Chemistry, 2021, 56 : 359 - 386
[4] Preparation and Properties of Films of Organic-Inorganic Perovskites MAPbX3 (MA = CH3NH3; X = Cl, Br, I) for Solar Cells: A Review
Belous, A. G.
Ishchenko, A. A.
V'yunov, O. I.
Torchyniuk, P. V.
THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2021, 56 (06) : 359 - 386
[5] Ultralow Thermal Conductivity and Ultrahigh Thermal Expansion of Single-Crystal Organic-Inorganic Hybrid Perovskite CH3NH3PbX3 (X = CI, Br, I)
Ge, Chunyu
Hu, Mingyu
Wu, Peng
Tan, Qi
Chen, Zhizhong
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Shi, Jian
Feng, Jing
JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (28): : 15973 - 15978
[6] Precise Molecular Design of High-TC 3D Organic-Inorganic Perovskite Ferroelectric: [MeHdabco]RbI3 (MeHdabco = N-Methyl-1,4-diazoniabicyclo[2.2.2]octane)
Zhang, Wan-Ying
Tang, Yuan-Yuan
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Ye, Heng-Yun
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Xiong, Ren-Gen
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (31) : 10897 - 10902
[7] Precise Molecular Design of High-Tc 3D Organic-Inorganic Perovskite Ferroelectric: [MeHdabco]RbI3 (MeHdabco = N-Methyl-1,4-diazoniabicyclo[2.2.2]octane)
Fu, Da-Wei (dawei@seu.edu.cn), 1600, American Chemical Society (139):
[8] Optical properties of photovoltaic materials: Organic-inorganic mixed halide perovskites CH3NH3Pb(I1-yXy)3 (X = Cl, Br)
Zhu, Sinan
Jiang, Miao
Ye, Jinting
Xie, Haiming
Qiu, Yongqing
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2018, 1144 : 1 - 8
[9] The structural, electronic, and optical properties of organic-inorganic mixed halide perovskites CH3NH3Pb(I1-yXy)3 (X = Cl, Br)
Jiang, Miao
Deng, Naihang
Wang, Li
Xie, Haiming
Qiu, Yongqing
CHINESE PHYSICS B, 2018, 27 (06)
[10] Room-temperature synthesis, growth mechanisms and opto-electronic properties of organic-inorganic halide perovskite CH3NH3PbX3 (X = I, Br, and Cl) single crystals
Bari, Maryam
Wu, Hua
Bokov, Alexei A.
Ali, Rana Faryad
Tailor, Hamel N.
Gates, Byron D.
Ye, Zuo-Guang
CRYSTENGCOMM, 2021, 23 (18) : 3326 - 3339

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