Enantiopure 1,1′-binaphthyl-based polyoxometalate-containing molecular hybrids

被引：42
|
作者：
Lu, M [1 ]
Kang, JH [1 ]
Wang, DG [1 ]
Peng, ZH [1 ]
机构：
[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 22期
关键词：
D O I：
10.1021/ic051129i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first chiral molecular hybrids based on covalently linked polyoxometalate clusters and enantiopure 1,1'-binaphthyl units have been prepared. Their structures have been confirmed by H-1 NMR, FTIR, and ESI-MS measurements. Such hybrids show moderate chiroptical behavior in solutions, and Cotton effects are observed up to 450 nm, indicating chiral extension from the binaphthyl core to the cluster-containing pi-conjugated arms.
引用
收藏
页码：7711 / 7713
页数：3
相关论文
共 50 条
  • [1] Enantiopure 1,1′-binaphthyl-based polyoxometalate-containing molecular hybrids (vol 44, pg 7711, 2005)
    Lu, M
    Kang, J
    Wang, DG
    Peng, ZH
    [J]. INORGANIC CHEMISTRY, 2005, 44 (26) : 9977 - 9977
  • [2] Synthesis of 1,1′-binaphthyl-based enantiopure C60 dimers
    Giacalone, F
    Segura, JL
    Martín, N
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (10): : 3529 - 3532
  • [3] Well-defined enantiopure 1,1′-binaphthyl-based oligomers:: Synthesis, structure, photophysical properties, and chiral sensing
    Ma, L
    White, PS
    Lin, WB
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (22): : 7577 - 7586
  • [4] Well-defined enantiopure 1,1′-binaphthyl-based oligomers:: Synthesis, photophysical properties, and chiral sensing.
    Lin, WB
    Ma, L
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U63 - U63
  • [5] Synthesis of new 1,1′-binaphthyl-based chiral phenylenevinylene dendrimers
    Díez-Barra, E
    García-Martínez, JC
    Rodríguez-López, J
    Gómez, R
    Segura, JL
    Martín, N
    [J]. ORGANIC LETTERS, 2000, 2 (23) : 3651 - 3653
  • [6] Synthesis and photoluminescent properties of 1,1′-binaphthyl-based chiral phenylenevinylene dendrimers
    Díez-Barra, E
    García-Martínez, JC
    del Rey, R
    Rodríguez-López, J
    Giacalone, F
    Segura, JL
    Martín, N
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (08): : 3178 - 3183
  • [7] 1,1'-binaphthyl-based polymers and dendrimers as electrical and optical materials.
    Pu, L
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U447 - U447
  • [8] Study of 1,1'-binaphthyl-based chiral Lewis acid catalysts.
    Pu, L
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U548 - U548
  • [9] Fluorescent Recognition of 1,2-Diamines by a 1,1′-Binaphthyl-Based Trifluoromethyl Ketone
    Xu, Yimang
    Yu, Shanshan
    Chen, Qi
    Chen, Xuemin
    Li, Yinan
    Yu, Xiaoqi
    Pu, Lin
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (34) : 12061 - 12067
  • [10] Recent advances in polyoxometalate-containing molecular conductors
    Coronado, E
    Giménez-Saiz, C
    Gómez-García, CJ
    [J]. COORDINATION CHEMISTRY REVIEWS, 2005, 249 (17-18) : 1776 - 1796
12345