Crystal structure of zdenekite NaPbCu5(AsO4)4Cl • 5H2O

被引：10
|
作者：
Zubkova, NV
Pushcharovsky, DY
Sarp, H
Teat, SJ
MacLean, EJ
机构：
[1] Moscow MV Lomonosov State Univ, Dept Geol, Moscow 119992, Russia
[2] Russian Acad Sci, Shubnikov Inst Crystallog, Moscow 119333, Russia
[3] Museum Nat Hist Geneva, Dept Mineral, CH-1208 Geneva, Switzerland
[4] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
来源：
CRYSTALLOGRAPHY REPORTS | 2003年 / 48卷 / 06期
关键词：
D O I：
10.1134/1.1627435
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the mineral zdenekite NaPbCu5(ASO(4))(4)Cl . 5H(2)O was established (Bruker SMART CCD diffractometer, synchrotron radiation, lambda = 0.6843 Angstrom, R = 0.096 for 1356 reflections). Single-crystal X-ray diffraction study demonstrated that zdenekite belongs to the monoclinic system with the unit-cell parameters a = 10.023(7) Angstrom, b = 19.55(1) Angstrom, c = 10.023(6) Angstrom, beta = 90.02(1)degrees, sp. cyr. P2(1)/n, Z = 4. The structure consists of polyhedral layers parallel to the (010) plane. These layers are formed by Cuphi(5) polyhedra (phi = O, Cl, H2O) and ASO(4) tetrahedra. Distorted Na octahedra and Pb 7-vertex. polyhedra and H2O molecules coordinated to these metal atoms are located between the layers. (C) 2003 MAIK "Nauka/Interperiodica".
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页码：939 / 943
页数：5
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