Novel coordination polymers with mixed ligands and orientated enantiomers

被引:61
|
作者
Shi, Z [1 ]
Feng, SH [1 ]
Sun, Y [1 ]
Hua, J [1 ]
机构
[1] Jilin Univ, Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
关键词
D O I
10.1021/ic015518y
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new coordination polymers, [Cu2(CyDTA)(4,4′-bipy)2]·12H2O (1) and [Cu3(EDTA)(4,4′-bipy)3.5(H2O)- (OH)2]·2H2O (2), were synthesized, and their crystal structures were determined by single-crystal X-ray diffraction. The coordination polymer of 1 has a novel double-layer network; two configurations for CyDTA are separated layer by layer. Another 3D structure of 2 is also presented for comparison.
引用
收藏
页码:5312 / 5313
页数:2
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