Synthesis, core-shell structures and properties of fluorene/polypyrrole composite

被引:1
|
作者
Song, Hui [1 ]
Li, Tingxi [1 ]
Han, Yongqin [1 ]
Cao, Guoqiang [1 ]
Wang, Yanmin [1 ]
Zhang, Chengxiang [1 ]
Wang, Qing [1 ]
机构
[1] Shandong Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266590, Peoples R China
关键词
HIGH-PERFORMANCE SUPERCAPACITOR; LITHIUM-ION BATTERIES; TEMPLATE-FREE METHOD; OPTICAL-PROPERTIES; POLYPYRROLE; NANOCOMPOSITES; HYBRID; FABRICATION; POLYANILINE; NANOFIBERS;
D O I
10.1134/S1560090417050128
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the current study, fluorene/polypyrrole composite with the core-shell structure has been synthesized by in situ oxidative polymerization of pyrrole in the presence of fluorene. Composite was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. Electrical performance of the composite prepared at various reaction conditions was tested. The composite has the best performance of electrical conductivity when FeCl3-pyrrole molar ratio is equal to 3 and the reaction time is 18 h. It was found that polypyrrole could be formed on the surface of fluorene due to strong pi-pi interactions between the fluorene core and the polypyrrole shell.
引用
收藏
页码:610 / 615
页数:6
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