The Composition and Interfacial Activity of Alkyl Benzene Sulfonates Used in Oil Recovery

被引：5
|
作者：
Wang, H. [1 ,2 ]
Zhang, D. [3 ]
Su, Y. [3 ]
Gang, H. [1 ,2 ]
Yang, S. [1 ,2 ]
Ye, R. [1 ,2 ]
Mu, B. [1 ,2 ]
机构：
[1] E China Univ Sci & Technol, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Inst Appl Chem, Shanghai 200237, Peoples R China
[3] Daqing Oilfield Ltd Co, Oil Prod Co 4, PetroChina, Daqing, Heilongjiang, Peoples R China
来源：
PETROLEUM SCIENCE AND TECHNOLOGY | 2015年 / 33卷 / 03期
基金：
中国国家自然科学基金;
关键词：
alkyl benzene sulfonates; separation; HPLC; mass spectrometry; interfacial activity; synergism; LINEAR ALKYLBENZENE SULFONATES; WATER SAMPLES; SPECTROMETRY; TENSIONS;
D O I：
10.1080/10916466.2013.872124
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The composition of heavy alkyl benzene sulfonates (HABS) was determined and the HABS was separated by a preparative HPLC. The surface and interfacial tensions of the components were measured. The results show that the HABS is a mixture of homologues, C(n)ABS, with different alkyl carbon numbers ranging from 12 to 25 on phenyl group. The CMC of six components, C(12)ABS, C(13)ABS, C(16)ABS, C(17)ABS, C(18)ABS, and C(19)ABS are 0.401-0.030 g.L-1. The C(16)ABS has the strongest interfacial activities. There occurred synergism between C(16)ABS and ionized organic acids in the crude oil produced by Na2CO3.
引用
收藏
页码：287 / 293
页数：7
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