Ethylene dimerization and polymerization over transition metal-exchanged montmorillonite catalysts

被引：1
|
作者：
Sohn, JR
Park, MY
机构：
[1] Department of Industrial Chemistry, Engineering College, Kyungpook National University
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1996年 / 57卷 / 02期
关键词：
clay catalyst; ethylene dimerization; ethylene polymerization; montmorillonite;
D O I：
10.1007/BF02064749
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It has been found that dimerization of ethylene to n-butenes proceeds selectively over Ni2+-Mont. Over Cr3+-Mont, extensive polymerization occurs and the polyethylene produced shows a high melting point and density. The catalytic activities for ethylene dimerization and polymerization are closely correlated with the acidity of catalysts.
引用
收藏
页码：361 / 373
页数：13
相关论文
共 50 条
  • [1] ETHYLENE POLYMERIZATION OVER TRANSITION METAL-EXCHANGED MONTMORILLONITE CATALYSTS
    SOHN, JR
    PARK, MY
    [J]. APPLIED CATALYSIS A-GENERAL, 1993, 101 (01) : 129 - 142
  • [2] Metal-exchanged zeolites as catalysts
    Armor, JN
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 22 (1-3) : 451 - 456
  • [3] Transition metal-exchanged LTA zeolites as novel catalysts for methane combustion
    Asedegbega-Nieto, Esther
    Diaz, Eva
    Vega, Aurelio
    Ordonez, Salvador
    [J]. CATALYSIS TODAY, 2010, 157 (1-4) : 425 - 431
  • [4] POLYMERIZATION OF ETHYLENE OVER TRANSITION-METAL EXCHANGED Y-ZEOLITES
    YASHIMA, T
    USHIDA, Y
    EBISAWA, M
    HARA, N
    [J]. JOURNAL OF CATALYSIS, 1975, 36 (03) : 320 - 326
  • [5] COMPARISON OF MODIFIED TRANSITION METAL-EXCHANGED ZEOLITE CATALYSTS FOR OXIDATION OF CHLORINATED HYDROCARBONS
    CHATTERJEE, S
    GREENE, HL
    PARK, YJ
    [J]. JOURNAL OF CATALYSIS, 1992, 138 (01) : 179 - 194
  • [6] KINETIC MODELING STUDIES OF TRANSITION METAL-EXCHANGED ZEOLITES AS CATALYSTS FOR REDOX REACTIONS
    APARICIO, LM
    DUMESIC, JA
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 49 (02): : 205 - 221
  • [7] Conversion of ethanol over metal-exchanged zeolites
    Schulz, Jurgen
    Bandermann, Friedhelm
    [J]. Chemical Engineering and Technology, 1993, 16 (05): : 332 - 337
  • [8] Metal-Exchanged β Zeolites as Catalysts for the Conversion of Acetone to Hydrocarbons
    Cruz-Cabeza, Aurora J.
    Esquivel, Dolores
    Jimenez-Sanchidrian, Cesar
    Romero-Salguero, Francisco J.
    [J]. MATERIALS, 2012, 5 (01) : 121 - 134
  • [9] NO and CO adsorption studies on transition metal-exchanged silico-aluminophosphate of type 34 catalysts
    Akolekar, DB
    Bhargava, SK
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 207 (1-2) : 355 - 365
  • [10] Selective photo-oxidation of benzene over transition metal-exchanged BEA zeolite
    Shimizu, K
    Akahane, H
    Kodama, T
    Kitayama, Y
    [J]. APPLIED CATALYSIS A-GENERAL, 2004, 269 (1-2) : 75 - 80
12345