Tripodal Phosphine Oxide Ligand with Tetrazole Functionality

被引：0

作者：

Baulina, T., V ^{[1
]}

Kudryavtsev, I. Yu ^{[1
]}

Bykhovskaya, O., V ^{[1
]}

Pasechnik, M. P. ^{[1
]}

Anikina, L., V ^{[1
]}

Vologzhanina, A. V. ^{[1
]}

Kochmarik, V. A. ^{[1
]}

Brel, V. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

tetrazole tripodal ligands; palladium(II) complexes; crystal structure; COORDINATION PROPERTIES; COMPLEXES; PLATFORM; EXTRACTION; CRYSTAL;

D O I：

10.1134/S1070363221100194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris[2-(3 '-cyanopropoxy)phenyl]phosphine oxide has been obtained via the alkylation of tris(2hydroxyphenyl)phosphine oxide with 4-bromobutyronitrile in the presence of K2CO3. The product structure has been elucidated by means of X-ray diffraction analysis. The terminal cyano groups in the obtained phosphine oxide have been converted into tetrazole rings via the click-reaction with NH4N3 to give a new hybrid tripodal propeller ligand, tris{2-[3 '-(tetrazol-5 ''-yl)propoxy]phenyl}phosphine oxide. Palladium(II) complexes of the prepared ligand and its short-linker analog, tris[2-(tetrazol-5 '-ylmethoxy)phenyl]phosphine oxide, have been synthesized. Cytotoxicity of the ligands and their Pd(II) complexes has been studied.

引用

页码：2052 / 2060

页数：9

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