Photocatalytic degradation of methyl orange on TiO2/biochar assisted by ionic liquids

被引:5
|
作者
Huang, Hsin-Liang [1 ]
Huang, Zi-Hao [1 ]
Tzeng, Ling-Syuan [1 ]
机构
[1] Natl United Univ, Dept Safety Hlth & Environm Engn, Miaoli 36063, Taiwan
关键词
Catalytic; Ti; Environmentally benign; Organic; Degradable; XPS; TIO2; SPECIATION;
D O I
10.1557/s43579-021-00106-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
TiO2 was synthesized on biochar derived from wood waste assisted by ionic liquids (1-butyl-3-methylimidazolium chloride ([C(4)mim]Cl) and 1-butyl-3-methylimidazolium tetrafluoroborate ([C(4)mim][BF4])). We compared the effects of photocatalysts synthesized with [C(4)mim]Cl (Ti-WB-Cl) and [C(4)mim][BF4] (Ti-WB-BF4) on the degradation of methyl orange. Using XRD, the nanoparticles of anatase TiO2 in Ti-WB-Cl and Ti-WB-BF4 were formed. Within 120 min under UV, the 88.1 and 99.8% of methyl orange were degraded, respectively. Moreover, by-products were barely observed using Ti-WB-BF4 photocatalyst. By XPS spectra, the Ti-WB-BF4 with carbon and fluorine incorporation suggests that enhanced photocatalytic degradation of methyl orange had occurred. Graphic abstract
引用
收藏
页码:838 / 842
页数:5
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