Synthesis and structural characterization of new weakly coordinating anions.: Crystal structure of Ag(1-CH3-CB11H5X6) (X = H, Cl, Br, I)

被引：25

作者：

Xie, ZW ^{[1
]}

Tsang, CW ^{[1
]}

Xue, F ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Hong Kong, NT, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 577卷 / 02期

关键词：

hexahalocarborane; lithiation; weakly coordinating anions;

D O I：

10.1016/S0022-328X(98)01040-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New weakly coordinating anions 1-CH3-CB11H5X6- = Cl, Br, I) have been prepared in high yield by either C-methylation of hexahalocarborane anions CB11H6X6- or direct halogenation of 1-CH3-CB11H11-. The lithiation of CB11H6X6- works just as well as that of the parent anion CB11H12- which offers a convenient method for the preparation of C-alkylated carborane anions of the type 1-R-CB11H5X6-. The useful silver(I) reagents of these new anions not only showed increased solubility in various organic solvents but also demonstrated the subtlety and diversity of their solid state structures. They are all one-dimensional coordination polymers in the solid state. The coordination details are, however, unique to each structure. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：197 / 204

页数：8

共 50 条

[1] Structural diversity in silver salts of hexahalogenocarborane anions, Ag(CB11H6X6) (X=Cl, Br or I)
Xie, ZW
Wu, BM
Mak, TCW
Manning, J
Reed, CA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (07): : 1213 - 1217
[2] Weakly coordinating nature of a carborane cage bearing different halogen atoms.: Synthesis and structural characterization of icosahedral mixed halocarborane anions, 1-H-CB11Y5X6- (X, Y=Cl, Br, I)
Tsang, CW
Yang, QC
Sze, ETP
Mak, TCW
Chan, DTW
Xie, ZW
[J]. INORGANIC CHEMISTRY, 2000, 39 (25) : 5851 - 5858
[3] Highly chlorinated, brominated, and iodinated icosahedral carborane anions:: 1-H-CB11X11-, 1-CH3-CB11X11- (X = Cl, Br, I); 1-Br-CB11Br11-
Xie, ZW
Tsang, CW
Sze, ETP
Yang, QC
Chan, DTW
Mak, TCW
[J]. INORGANIC CHEMISTRY, 1998, 37 (25) : 6444 - 6451
[4] Electrochemistry with the extremely weak coordinating anions: Using of carboranes [H-CB11X6Y5]- (X = H, Cl, Br; Y = H or Me) as supporting electrolyte anions
Nafady, Ayman
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 755 : 1 - 6
[5] Synthesis and crystal structure of silver and argentate complexes of mixed halocarborane anions, (C5H5N)2Ag(1-H-CB11Br5I6)(C5H5N) and [{(CH3CN)4Ag3}{Ag(CB11I5Br6)2}]n
Tsang, CW
Yang, QC
Mak, TCW
Xie, ZW
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (6-7) : 449 - 452
[6] Chlorination of icosahedral carborane anions. X-ray crystal structure of [Me3NH][CH3-1-CB11Cl11]
Xie, ZW
Tsang, CW
Xue, F
Mak, TCW
[J]. INORGANIC CHEMISTRY, 1997, 36 (11) : 2246 - 2247
[7] Synthesis and structural characterization of highly chlorinated, brominated, iodinated, and methylated carborane anions, 1-H-CB9X9-, 1-NH2-CB9X9- (X = Cl, Br, I), and 1-H-CB9(CH3)9-
Tsang, CW
Yang, QC
Sze, ETP
Mak, TCW
Chan, DTW
Xie, ZW
[J]. INORGANIC CHEMISTRY, 2000, 39 (16) : 3582 - 3589
[8] Salts of the 1-cyanocarba-closo-dodecaborate anions [1-NC-closo-1-CB11X11]- (X = H, F, Cl, Br, I)
Finze, Maik
Sprenger, Jan A. P.
Schaack, Bernd Bastian
[J]. DALTON TRANSACTIONS, 2010, 39 (10) : 2708 - 2716
[9] Highly fluorinated weakly coordinating monocarborane anions.: 1-H-CB11F11-, 1-CH3-CB11F11-, and the structure of [N(n-Bu)4]2[CuCl(CB11F11)]
Ivanov, SV
Rockwell, JJ
Polyakov, OG
Gaudinski, CM
Anderson, OP
Solntsev, KA
Strauss, SH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (17) : 4224 - 4225
[10] Highly fluorinated weakly coordinating monocarborane anions.: 1-H-CB11F11-, 1-CH3-CB11F11-, and the structure of [N(n-Bu)4]2[CuCl(CB11F11)].
Ivanov, SV
Rockwell, JJ
Polyakov, OG
Gaudinski, CM
Anderson, OP
Solntsev, KA
Strauss, SH
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U735 - U735

← 1 2 3 4 5 →