Synthesis, Structure, Thermal and Fluorescent Properties of a Novel Mn(II) Coordination Polymer and its Hexacyclic Water Ring

被引：3

作者：

Zhuang, Yue ^{[1
]}

Yin, Xian-Hong ^{[1
]}

Li, Peng-fei ^{[1
]}

Hu, Fei-Long ^{[1
]}

Zhang, Shan-Shan ^{[1
]}

机构：

[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Nanning 530006, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2012年 / 42卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Manganese (II) complex; Water clusters; Crystal structure; Thermal stability; CRYSTAL-STRUCTURE; CLUSTERS; COMPLEX; HEXAMERS; DESIGN;

D O I：

10.1007/s10870-011-0193-5

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A novel Imazethapyr-bridged complex [Mn(Ima)(2)] (H2O)(2) (1) [Imazethapyr (Ima)=5-ethyl-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl) nicotinic acid, has been synthesized and structurally characterized by X-ray diffraction method, infrared spectra, elemental analysis and thermal analysis. The title polymer contains a monocyclic hexamer water cluster, and the cluster plays an important role in stabilizing the complex. The fluorescence of the complex 1 in the solid state was investigated via FL55 spectrophotometer and it indicated a fluorescent behavior at room temperature.

引用

页码：18 / 23

页数：6

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