Comment on "Flat band potential determination: avoiding the pitfalls" by A. Hankin, F. E. Bedoya-Lora, J. C. Alexander, A. Regoutz and G. H. Kelsall, J. Mater. Chem. A, 2019, 7, 26162

被引:1
|
作者
Diez-Garcia, Maria, I
Monllor-Satoca, Damian
Gomez, Roberto [1 ]
机构
[1] Univ Alacant, Dept Quim Fis, Apartat 99, E-03080 Alicante, Spain
基金
美国国家卫生研究院; 加拿大健康研究院;
关键词
MOTT-SCHOTTKY ANALYSIS;
D O I
10.1039/d1ta06474f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this comment, it is shown that the work published by Hankin et al. [Hankin et al., J. Mater. Chem. A, 2019, 7, 26162-26176], while mostly timely and appropriate, present two mistakes that are discussed in detail. First, the determination of flat band potentials through a Mott-Schottky analysis is in principle not affected by the existence of a real surface area substantially larger than the geometric surface area and, second, the Gartnet-Butler model may not be applicable for electrodes with high values of the absorption coefficient and low dopant density values.
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页码:8591 / 8593
页数:3
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