Preparation and Properties of Novel Double-Chain Nonionic Surfactants with Acid Decomposition Function

被引：4
|
作者：
Ono, Daisuke [1 ]
Sato, Hirofumi [1 ]
Shizuma, Motohiro [1 ]
Nakamura, Masaki [1 ]
机构：
[1] Osaka Municipal Tech Res Inst, Joto Ku, Osaka 5368553, Japan
来源：
JOURNAL OF OLEO SCIENCE | 2010年 / 59卷 / 07期
基金：
日本学术振兴会;
关键词：
chemocleavable surfactants; acetal type; nonionic surfactants; double-chain surfactants; biodegradation; CHEMODEGRADABLE ANIONIC SURFACTANTS; CLEAVABLE SURFACTANTS; 1,3-DIOXOLANE RING; BEARING; GLUCONO-1,5-LACTONE;
D O I：
10.5650/jos.59.381
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Novel double-chain nonionic surfactants with an acid decomposition function were prepared by acid-catalyzed condensation of chloroacetone with fatty alcohols (octyl, decyl, and dodecyl), followed by a Williamson reaction with polyethylene glycol without any expensive reagents and special equipment. These surfactants showed easy micelle formation compared to those of polyoxyethylene (n=9) dodecyl ether (C(12)EO9), and good foaming properties. The emulsion stability of these surfactants was almost the same as that of C(12)EO9. They decomposed completely after 30 min at pH 1. After 28 days they were more than 60% biodegradable and were almost the same as sodium dodecanoate.
引用
收藏
页码：381 / 386
页数：6
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