Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry

被引：106

作者：

Ma, Cong ^{[1
]}

Zhao, Chuan-Qi ^{[1
]}

Li, Yi-Qian ^{[2
,3
]}

Zhang, Li-Pu ^{[2
,3
]}

Xu, Xue-Tao ^{[2
,3
]}

Zhang, Kun ^{[2
,3
]}

Mei, Tian-Sheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Wuyi Univ, Sch Chem & Environm Engn, Jiangmen 529020, Peoples R China

[3] Int Healthcare Innovat Inst Jiangmen, Jiangmen 529000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 90期

关键词：

DECARBOXYLATIVE ORTHO-ACYLATION; ALKYLBORONIC ACIDS; ALKYLATION; FUNCTIONALIZATION; OXIDATION; ESTERS; BOND; BENZOQUINONE; COMPLEXES; ARYLATION;

D O I：

10.1039/c7cc07429h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation.

引用

页码：12189 / 12192

页数：4

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