Batch conditions were optimized for the sorption of aniline and toluidines from the air on polystyrene, polyethyleneglycol-2000, and polyethyleneglycol succinate using piezoelectric microweighing. It was found that the analytical signal of a quartz crystal resonator depended on the mass of the modifier on the electrode surface and on the solvent. The selectivity of modifiers with respect to the compounds studied was estimated.