Comparative study of simulated zirconia inert matrix fuel stabilized with yttrium, lanthanum or praseodymium:: Synthesis and leaching tests

Stabilized zirconia inert matrix fuels were synthesized with different lanthanides: yttrium, lanthanum and praseodymium. The materials were sintered in air at 1723 K. Cerium, an analog element of plutonium and americium, was employed to simulate a minor actinide in the process development, owing to the high activity of minor actinides. For each matrix, several properties, such as crystalline structure, density, microhardness, specific area, microstructure and corrosion behaviour were measured. The best materials were those crystallized in a face centred cubic system, with the compositions: (Zr0.73Y0.14Er0.05Ce0.08)O-2, (Zr0.73La0.14Er0.05Ce0.08)O-2 and (Zr0.73Pr0.05Er0.07Ce0.15)O-2. Lanthanum stabilized zirconia materials were the best. The corrosion tests showed that the whole of materials has a satisfactory chemical stability. (C) 2005 Elsevier Ltd. All rights reserved.