A Trisheteroleptic Cyclometalated RuII Sensitizer that Enables High Power Output in a Dye-Sensitized Solar Cell

被引：116
|
作者：
Bomben, Paolo G. [1 ,2 ]
Gordon, Terry J. [1 ,2 ]
Schott, Eduardo [3 ]
Berlinguette, Curtis P. [1 ,2 ]
机构：
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
[2] Univ Calgary, Ctr Adv Solar Mat, Calgary, AB T2N 1N4, Canada
[3] Univ Andres Bello, Dept Ciencias Quim, Santiago, Chile
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 45期
基金：
加拿大自然科学与工程研究理事会;
关键词：
cobalt; donor-acceptor systems; energy conversion; ruthenium; sensitizers; LIGHT-HARVESTING APPLICATIONS; RUTHENIUM(II) COMPLEXES; REDOX SHUTTLES; DESIGN; STABILITY; TRANSPORT; COUPLE;
D O I：
10.1002/anie.201104275
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A trisheteroleptic cyclometalated ruthenium complex (see picture) bearing aliphatic substituents was synthesized, characterized, and evaluated in a dye-sensitized solar cell (DSSC). This thiocyanate-free dye, which has favorable structural elements to exhibit long-term stability, generates a high power output in the DSSC with both iodide-based and Co-based redox shuttles. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10682 / 10685
页数：4
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