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Well-aligned NiPt alloy counter electrodes for high-efficiency dye-sensitized solar cell applications
被引:26
|作者:
Pang, Zhibin
[1
,2
]
Zhao, Yuanyuan
[1
]
Duan, Yanyan
[1
]
Duan, Jialong
[1
]
Tang, Qunwei
[1
]
Yu, Liangmin
[2
]
机构:
[1] Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266100, Shandong, Peoples R China
[2] Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Shandong, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Dye-sensitized solar cell;
Counter electrode;
Alloy electrocatalyst;
POLYANILINE;
PERFORMANCE;
POWER;
COST;
D O I:
10.1016/j.jechem.2018.03.016
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
Development of cost-effective and robust counter electrodes (CEs) is a persistent objective for highefficiency dye-sensitized solar cells (DSSCs). To achieve this goal, we present here the hydrothermal synthesis of well-aligned NiPt alloy CEs, which is templated by ZnO nanowires and nanosheets. The preliminary results demonstrate that NiPt alloy electrodes are featured by increased charge-transfer processes and electrocatalytic activity in comparison with expensive Pt CE, yielding power conversion efficiencies of 8.29% and 7.41% in corresponding DSSCs with NiPt nanowire and nanosheet alloy CEs, respectively. Additionally, the NiPt alloy CEs also display extraordinary dissolution-resistant ability when suffering long-term utilization in liquid-junction DSSCs. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
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页码:49 / 56
页数:8
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