Employing Cd-O-C rod-shaped secondary building units to construct 2D metal-organic frameworks (MOFs): hydrothermal synthesis, structures, and luminescent properties

被引：15
|
作者：
Luo, Feng [1 ]
Che, Yun-Xia [1 ]
Zheng, Ji-Min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 13期
基金：
中国国家自然科学基金;
关键词：
hydrothermal synthesis; MOFs; SBUs; inorganic-organic rod structure;
D O I：
10.1080/00958970701870186
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Under hydrothermal conditions, in the presence of H(2)BDC, the self-assembly of CdCl(2), H(2)ip or H(2)NDC at pH = 7 generated two Cd(II)-containing coordination polymers, Cd(6)(ip)(6)(mu-H(2)O)(4) center dot H(2)O (1) and Cd(2)(NDC)(2)(mu-H(2)O)(2) (2) (H(2)BDC/H(2)ip/H(2)NDC = 1,4/1,3/1,2-benzenedicarboxylic acid). The structures are 2D metal-organic frameworks constructed from Cd-O-C rod-shaped SBUs (Secondary Building Units). Crystal samples in the solid state display strong fluorescence at 335 and 343 nm.
引用
收藏
页码：2097 / 2104
页数：8
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