Synthesis of Uniform-Size Hollow Silica Microspheres through Interfacial Polymerization in Monodisperse Water-in-Oil Droplets

被引：46

作者：

Li, Dianyan

Guan, Zhichao

Zhang, Wenhua

Zhou, Xi

Zhang, Wei Yun

Zhuang, Zhixia

Wang, Xiaoru

Yang, Chaoyong James ^{[1
]}

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Key Lab Analyt Sci, Key Lab Chem Biol Fujian Prov,Coll Chem & Chem En, Xiamen 361005, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2010年 / 2卷 / 10期

关键词：

silica microspheres; morphology; microfluidic; interfacial reaction; detoxification; EMULSION SYSTEM; SPHERES; SHELL; MICROCAPSULES; FABRICATION; PARTICLES; RELEASE; STORAGE; DRUG; NANOPARTICLES;

D O I：

10.1021/am100593b

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We have developed a microfluidic method to produce monodisperse, size-controllable silica microspheres via hydrolysis and polymerization of TEOS at the interface of water-in-oil droplets. By altering the concentration of TEOS in oil phase and CTAB in aqueous phase, we achieved control over morphology of the microspheres from hollow, to partly hollow, to solid. The hollow silica microsphere can be used for rapid waste removal and detoxification extraction with a very simple procedure.

引用

页码：2711 / 2714

页数：4

共 13 条

[1] Synthesis of glycylglycine-imprinted silica microspheres through different water-in-oil emulsion techniques
Ornelas, Mariana
Loureiro, Dianne
Araujo, Maria Joao
Marques, Eduardo
Dias-Cabral, Cristina
Azenha, Manuel
Silva, Fernando
[J]. JOURNAL OF CHROMATOGRAPHY A, 2013, 1297 : 138 - 145
[2] Production of monodisperse water-in-oil emulsions consisting of highly uniform droplets using asymmetric straight-through microchannel arrays
Kobayashi, Isao
Murayama, Yoichi
Kuroiwa, Takashi
Uemura, Kunihiko
Nakajima, Mitsutoshi
[J]. MICROFLUIDICS AND NANOFLUIDICS, 2009, 7 (01) : 107 - 119
[3] Production of monodisperse water-in-oil emulsions consisting of highly uniform droplets using asymmetric straight-through microchannel arrays
Isao Kobayashi
Yoichi Murayama
Takashi Kuroiwa
Kunihiko Uemura
Mitsutoshi Nakajima
[J]. Microfluidics and Nanofluidics, 2009, 7
[4] Preparation of water-in-oil emulsions using microporous polypropylene hollow fibres:: Conditions for producing small uniform droplets
Vladisavljevic, GT
Brösel, S
Schubert, H
[J]. CHEMICAL PAPERS, 2000, 54 (6A) : 383 - 388
[5] Preparation of uniform and porous polyurea microspheres of large size through interfacial polymerization of toluene diisocyanate in water solution of ethylene diamine
Zhang, Feilong
Jiang, Xubao
Zhu, Xiaoli
Chen, Zhiyong
Kong, Xiang Zheng
[J]. CHEMICAL ENGINEERING JOURNAL, 2016, 303 : 48 - 55
[6] Preparation of uniform and porous polyurea microspheres of large size through interfacial polymerization of toluene diisocyanate in water solution of ethylene diamine
[J]. Jiang, Xubao (chm_jiangxb@ujn.edu.cn), 1600, Elsevier B.V., Netherlands (303):
[7] Facile synthesis of monodisperse microspheres and gigantic hollow shells of mesoporous silica in mixed water-ethanol solvents
Zhang, Huijuan
Wu, Jun
Zhou, Longping
Zhang, Dayong
Qi, Limin
[J]. LANGMUIR, 2007, 23 (03) : 1107 - 1113
[8] Preparation of Mannitol@Silica core-shell capsules via an interfacial polymerization process from water-in-oil emulsion
Wu, Chang-Bo
Wu, Gang
Yang, Xi
Liu, Yu-Jing
Gao, Chen-Xi
Ji, Qi-Hua
Wang, Mang
Chen, Hong-Zheng
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2014, 457 : 487 - 494
[9] Flow synthesis of monodisperse micron-sized polymer particles by heterogeneous polymerization using a water-in-oil slug flow with a non-ionic surfactant
Watanabe, Takaichi
Karita, Kengo
Ono, Tsutomu
[J]. COLLOID AND POLYMER SCIENCE, 2020, 298 (09) : 1273 - 1281
[10] Flow synthesis of monodisperse micron-sized polymer particles by heterogeneous polymerization using a water-in-oil slug flow with a non-ionic surfactant
Takaichi Watanabe
Kengo Karita
Tsutomu Ono
[J]. Colloid and Polymer Science, 2020, 298 : 1273 - 1281

← 1 2 →