Impact of Coumarin on Optical, Structural and Thermal Properties of TiO2@ZnO core-shell filled PMMA matrix

被引:2
|
作者
Nandimath, Madhavi [1 ]
Bhajantri, R. F. [1 ]
Naik, Jagadish [1 ]
Hebbar, Vidyashree [1 ]
机构
[1] Karnatak Univ, Dept Phys, Dharwad 580003, Karnataka, India
来源
关键词
SPECTRAL CHARACTERISTICS;
D O I
10.1063/1.5112913
中图分类号
O59 [应用物理学];
学科分类号
摘要
The polymer composites of coumarin doped TiO2@ZnO/PMMA were prepared and their structural, morphological, optical and thermal properties have been examined by Fourier Transform Infrared (FTIR) Spectroscopy, Atomic Force Microscopy (AFM), UV-Visible absorption (UV-Vis) and Differential Scanning Calorimetry (DSC). The interaction between poly(methyl methacrylate) (PMMA) and coumarin is confirmed by FTIR results. The surface morphology of prepared composites is analyzed using AFM. The UV-Visible spectra show two peaks at 230 nm and 261 nm attributed to n-pi* transition that arises due to existence of carbonyl groups (-C=O- or -C=C-) in PMMA and another peak is observed at 312 nm after doping of coumarin, which is attributed to pi-pi* transition. DSC thermograms have shown almost constant degradation temperature at 370 degrees C for all samples. Hence, the prepared composites have shown good structural and optical properties, may be used in optoelectronic applications.
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页数:4
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