SOFC and MCFC: Commonalities and opportunities for integrated research

被引:76
|
作者
McPhail, Stephen J. [1 ]
Aarva, Anja [2 ]
Devianto, Hary [1 ]
Bove, Roberto [3 ]
Moreno, Angelo [1 ]
机构
[1] ENEA Energy Dept Hydrogen & Fuel Cells, I-00123 Rome, Italy
[2] Aalto Univ, Espoo, Finland
[3] Alstom Power, Birr, Switzerland
关键词
Contaminant poisoning; Sulphur; Carbon deposition; High-temperature fuel cell materials; CARBON DEPOSITION; FUEL-CELLS; OXIDE; ANODES; NI; SULFUR; HYDROCARBONS; ELECTRODE; METHANE; CH4;
D O I
10.1016/j.ijhydene.2010.09.071
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present article explores the key issues for research and development that are common to current state-of-the-art MCFC and SOFC technologies. By analyzing overlapping aspects regarding materials, operating conditions and applications of the two types of hightemperature fuel cell (HTFC), the most pressing common challenges are set forth. Similarities between the MCFC and SOFC exist especially on the anode side, given their utilization of nickel as the oxidation catalyst and their suitability for conversion of hydrocarbon fuel. Catalyst deactivation due to contaminant poisoning and carbon deposition thereby emerges as the crucial problem to overcome. A brief review of these mechanisms is given and of relevant studies in the field of HTFCs. The implications on the HTFC catalyst material given by this review are summarized and put forward as lines of research that can be undertaken jointly by players both in MCFC and SOFC development. Copyright (C) 2010, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:10337 / 10345
页数:9
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