New application of bromotrimethylsilane:: Elaboration of aldehydes/ketones into homologous α,β-unsaturated esters via β-hydroxy esters

被引：2
|
作者：
Suri, SC [1 ]
Marcischak, JC [1 ]
机构：
[1] Air Force Res Lab PRSP, Edwards AFB, CA 93524 USA
来源：
SYNTHETIC COMMUNICATIONS | 2005年 / 35卷 / 03期
关键词：
bromotrimethylsilane; beta-hydroxy ester; reformatsky reaction; alpha; beta-unsaturated ester; beta; gamma-unsaturated ester;
D O I：
10.1081/SCC-200048941
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha, beta-Unsaturated esters are formed when beta-hydroxy esters react with bromotrimethylsilane which is generated from chlorotrimethylsilane-lithium bromide in acetonitrile.
引用
收藏
页码：379 / 387
页数：9
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