Functional property optimization of sodium caseinate-based films incorporating functional compounds from date seed co-products using response surface methodology

Novel composite films made of sodium caseinate (NaCas) and two functional compounds from date seed co-products, i.e. furfural and date seed oil (DSO), were produced. The effects of furfural and DSO contents on the barrier, mechanical and optical properties of NaCas films were assessed using a two-factor, five-level central composite design. Increasing DSO content increased contact angle values of NaCas films and decreased their solubility indicating an increase in their hydrophobicity. Moreover, increasing furfural concentration increased tensile strength (TS) of NaCas films due to crosslink formation between furfural and NaCas' primary amine groups. On the other hand, furfural and DSO incorporation conferred good light barrier properties to the resulting films. Overall, a furfural content of 0.69% and 1.76% DSO were selected as the optimum factor levels producing maximum contact angle (69.85 degrees) and TS (36.47 MPa) and minimum solubility (16.95%) with overall desirability of 0.98.