Monte Carlo simulations of grafted chains at interfaces

被引:0
|
作者
Sahlin, JJ [1 ]
Peppas, NA [1 ]
机构
[1] PURDUE UNIV,SCH CHEM ENGN,POLYMER SCI & ENGN LABS,W LAFAYETTE,IN 47907
关键词
simulations; gel/gel adhesion; chain interpenetration; grafting;
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Simulations were carried out of the polymer-polymer chain interpenetration, diffusion, and adhesion of crosslinked polymers with dangling chain ends. Concentration profiles were determined for various polymer chain lengths and densities. The penetration depth was less than the radius of gyration of the polymer grafts or dangling ends and was a function of the packing density and the graft segment length. Limited chain mobility created a stable interfacial zone. (C) 1997 John Wiley & Sons, Inc.
引用
收藏
页码:547 / 551
页数:5
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