Visible light-controlled reversible self-assembly of nanorod supramolecular structures

被引:2
|
作者
Huang, Minyan [1 ]
Meng, Juxiang [1 ]
Li, Zhongyu [1 ,2 ]
Xu, Song [1 ]
机构
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China
[2] Changzhou Univ, Jiangsu Adv Catalysis & Green Mfg Collaborat Inno, Changzhou 213164, Jiangsu, Peoples R China
来源
OPTIK | 2020年 / 203卷 / 203期
基金
中国国家自然科学基金;
关键词
Visible light controlled; Supramolecular structure; Merocyanine; Self-assembly process; BETA-CYCLODEXTRIN; INCLUSION COMPLEX; RECOGNITION; AMPHIPHILES; PH;
D O I
10.1016/j.ijleo.2019.164075
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In this article, a nanorod suprastructure constructed by coordination of calcium ions (Ca2+) with complex beta-cyclodextrin-4,4'-dipyridyl (B-44) in the presence of the photo-acid merocyanine (MEH). The suprastructure (B-44-Ca) possesses reversible photoswitching with high on/off contrast based on the self-assembly process in aqueous solution. In which, the supramolecular can be activated by visible-light instead of acid or base. The system not only can be carried by remote control, but also by the introduction of additional chemicals, which will facilitate the reversibility of light-controlled supramolecular smart materials.
引用
收藏
页数:7
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