Applying the B/N Lewis Pair Approach to Access Fusion-Expanded Binaphthyl-Based Chiral Analogues

被引：2

作者：

Tian, Guoqing ^{[1
,2
]}

Chen, Jin-Fa ^{[1
,2
]}

Zhang, Kai ^{[1
,2
]}

Shi, Yafei ^{[1
,2
]}

Li, Chenglong ^{[1
,2
]}

Yin, Xiaodong ^{[1
,2
]}

Liu, Kanglei ^{[1
,2
]}

Chen, Pangkuan ^{[1
,2
]}

机构：

[1] Beijing Inst Technol China, Minist Educ, Beijing Key Lab Photoelect Electrophoton Convers M, Key Lab Cluster Sci, Beijing 102488, Peoples R China

[2] Beijing Inst Technol China, Minist Ind & Informat Technol, Sch Chem & Chem Engn, Key Lab Med Mol Sci & Pharmaceut Engn, Beijing 102488, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年

基金：

中国国家自然科学基金;

关键词：

OPTOELECTRONIC PROPERTIES; CHIROPTICAL PROPERTIES; LIGHT; BORON; LUMINESCENCE; DESIGN; NUMBER; ACENES;

D O I：

10.1021/acs.inorgchem.2c02875

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We herein describe the synthesis of two axially chiral systems (HBN and BBN) by the incorporation of B centers into binaphthyl derivatives (HPy and BPy). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.

引用

页码：15315 / 15319

页数：5