Ethylene to Propylene by One-Pot Catalytic Cascade Reactions

被引：40

作者：

Andrei, Radu Dorin ^{[1
,2
]}

Popa, Marcel Ionel ^{[2
]}

Fajula, Francois ^{[1
]}

Cammarano, Claudia ^{[1
]}

Al Khudhair, Atheer ^{[1
]}

Bouchmella, Karim ^{[1
]}

Mutin, P. Hubert ^{[1
]}

Hulea, Vasile ^{[1
]}

机构：

[1] CNRS UM2 ENSCM UM1, UMR 5253, Inst Charles Gerhardt Montpellier, F-34296 Montpellier 5, France

[2] Tech Univ Iasi, Fac Chem Engn & Environm Protect, Iasi 700050, Romania

来源：

ACS CATALYSIS | 2015年 / 5卷 / 05期

关键词：

tandem catalysis; heterogeneous catalysis; oligomerization; metathesis; Al-SBA-15; nonhydrolytic sol-gel; HIGHLY SELECTIVE CONVERSION; ZIEGLER-NATTA CATALYSIS; HYDROLYTIC SOL-GEL; OLEFIN METATHESIS; ORGANIC-SYNTHESIS; OXIDE CATALYSTS; DIMERIZATION; PROPENE; ETHENE; OLIGOMERIZATION;

D O I：

10.1021/acscatal.5b00383

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An original method for converting ethylene to propylene involving cascade oligomerization/isomerization/metathesis reactions over two robust and highly active heterogeneous catalysts is investigated. In a single flow reactor and under identical conditions, ethylene was first selectively dimerized/isomerized over Ni-AlSBA-15 catalyst to form 2-butenes, which reacted then with the excess of ethylene over MoO3-SiO2-Al2O3 to produce propylene. At 80 degrees C and 3 MPa, specific activities up to 48 mmol of propylene per gram of catalyst per hour were obtained.

引用

页码：2774 / 2777

页数：4

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