An efficient B/Na co-doped porous g-C3N4 nanosheets photocatalyst with enhanced photocatalytic hydrogen evolution and degradation of tetracycline under visible light

被引:44
|
作者
Chi, Xianhu [1 ,2 ]
Liu, Fengjiao [1 ]
Gao, Yan [1 ]
Song, Jun [1 ]
Guan, Rongfeng [1 ]
Yuan, Haibin [2 ]
机构
[1] Yancheng Inst Technol, Key Lab Adv Technol Environm Protect Jiangsu Prov, Yancheng, Jiangsu, Peoples R China
[2] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
g-C3N4; Doping; Hydrogen evolution; Antibiotic degradation; GRAPHITIC CARBON NITRIDE; ONE-STEP SYNTHESIS; Z-SCHEME PHOTOCATALYST; ULTRATHIN NANOSHEETS; H-2; PRODUCTION; CONSTRUCTION; PERFORMANCE; CATALYST; FE; PHOTODEGRADATION;
D O I
10.1016/j.apsusc.2021.151837
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
g-C3N4 has attracted wide concern owing to its function of photocatalytic degradation of pollutants and H-2 production. However, the bulk carbon nitride (BCN) has many shortcomings, such as poor light absorption ability, short life of photogenerated electrons and few reactive sites. In this study, element doping and morphology control strategies were used to enhance their activity. B/Na co-doped porous carbon nitride nanosheets (PNCN-BNa-3) were successfully prepared by controlling the heating rate and thermal post-treatment using melamine nitrate as precursor, sodium borohydride as B source and Na source. Thanks to the synergistic effect of the porous nanosheets structure and B/Na co-doped, the B/Na co-doped porous g-C3N4 nanosheets obtained wonderful photocatalytic hydrogen generation properties (5971.51 mu mol.g(-1).h(-1)), AQE value of 9.39% under the radiation of 430 nm wavelength, and high-efficiency photocatalytic removal of TC performance (the removal efficiency reached 78.39% in 30 min). This provides a new idea for the preparation of semiconductor photocatalysts with good property.
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页数:9
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