Solution of the Inverse Problem by Stationary Data for Chemical Reactions with Nonideal Kinetics

被引：2

作者：

Kol'tsov, N., I ^{[1
]}

机构：

[1] Ulyanov Chuvash State Univ, Fac Chem & Pharmaceut, Cheboksary 428015, Russia

来源：

KINETICS AND CATALYSIS | 2021年 / 62卷 / 04期

关键词：

chemical reactions; stationary experiments; nonideal kinetics; inverse problem; rate constants; gradientless reactor; DE-DONDER KINETICS; INVARIANTS;

D O I：

10.1134/S0023158421040042

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method for solving the inverse problem of chemical kinetics based on stationary data for chemical reactions proceeding according to nonideal kinetic laws in an isothermal gradientless reactor was developed. The estimation of the rates constants of reaction stages in terms of the Marcelin-de Donder kinetics different from mass action kinetics was exemplified. The results obtained expand the understanding of the possibility of solving the inverse problem of chemical kinetics by stationary data taking into account the influence of nonideal factors.

引用

页码：446 / 450

页数：5

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