Temperature-dependent ferroelectric hysteresis properties of modified lead zirconate titanate ceramics

被引：39
|
作者：
Wen, Baohua [2 ]
Zhang, Yong [1 ]
Liu, Xiaolin [2 ]
Ma, Liang [1 ]
Wang, Xiangrong [1 ]
机构：
[1] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing Fine Ceram Lab, Beijing 100084, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
来源：
JOURNAL OF MATERIALS SCIENCE | 2012年 / 47卷 / 10期
基金：
中国国家自然科学基金;
关键词：
THIN-FILMS; BULK CERAMICS; CAPACITORS; BEHAVIOR; KINETICS;
D O I：
10.1007/s10853-012-6280-y
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Temperature-dependent ferroelectric hysteresis properties of modified lead zirconate titanate ceramics have been investigated in a wide temperature range from 300 to 433 K. It is observed that remnant polarization, saturation polarization, and coercive field are increasing with an increase of the temperature in a low-field region and decreasing in a high-field region. Such behavior is explained by the competition between switching and backswitching mechanisms. A three-stage dependence of the logarithm of the hysteresis loop area on the logarithm of the electric field is identified. The temperature dependence of backswitching properties has been studied. The obtained results indicate that the temperature dependence of the polarization backswitching can be well described by the Arrhenius law. The activation energy for the domain switching determined from the fitting results exhibits decreasing tendency with the increase of the electric field.
引用
收藏
页码：4299 / 4304
页数：6
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