Highly Selective Conversion of Carbon Dioxide to Lower Olefins

被引:484
|
作者
Li, Zelong [1 ]
Wang, Jijie [1 ]
Qu, Yuanzhi [1 ]
Liu, Hailong [1 ]
Tang, Chizhou [1 ]
Miao, Shu [1 ]
Feng, Zhaochi [1 ]
An, Hongyu [1 ]
Li, Can [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源
ACS CATALYSIS | 2017年 / 7卷 / 12期
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
tandem catalysis; CO2; hydrogenation; C-C coupling; thermodynamic coupling; solid solution oxide; METAL-ORGANIC FRAMEWORKS; CO2; HYDROGENATION; METHANOL SYNTHESIS; BIFUNCTIONAL CATALYSTS; HYDROCARBON SYNTHESIS; PRODUCT SELECTIVITY; HYBRID CATALYSTS; LIGHT OLEFINS; SYNTHESIS GAS; SYNGAS;
D O I
10.1021/acscatal.7b03251
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Conversion of CO2 to value-added chemicals has been a long-standing objective, and direct hydrogenation of CO2 to lower olefins is highly desirable but still challenging. Herein, we report a selective conversion of CO2 to lower olefins through CO2 hydrogenation over a ZnZrO/SAPO tandem catalyst fabricated with a ZnO-ZrO, solid solution and a Zn-modified SAPO-34 zeolite, which can achieve a selectivity for lower olefins as high as 80-90% among hydrocarbon products. This is realized on the basis of the dual functions of the tandem catalyst: hydrogenation of CO2 on the ZnO-ZrO2, solid solution and lower olefins production on the SAPO zeolite. The thermodynamic and kinetic coupling between the tandem reactions enable the highly efficient conversion of CO2 to lower olefins. Furthermore, this catalyst is stable toward the thermal and sulfur treatments, showing the potential industrial application.
引用
收藏
页码:8544 / 8548
页数:5
相关论文
共 50 条
  • [1] Highly Selective Photoelectrochemical Conversion of Carbon Dioxide to Formic Acid
    Jiang, Mengpei
    Wu, Hongjun
    Li, Zhida
    Ji, Deqiang
    Li, Wei
    Liu, Yue
    Yuan, Dandan
    Wang, Baohui
    Zhang, Zhonghai
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (01): : 82 - 87
  • [2] Highly selective photocatalytic conversion of carbon dioxide and water into methane
    Chen, Yongjun
    Thamban, Arun
    Nguyen, Mark T.
    Menkara, Hisham
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [4] HIGHLY SELECTIVE CONVERSION OF TERMINAL OLEFINS INTO ALDEHYDES
    BROWN, HC
    KULKARNI, SU
    RAO, CG
    SYNTHESIS-STUTTGART, 1980, (02): : 151 - 152
  • [5] Highly Selective Conversion of Carbon Dioxide to Aromatics over Tandem Catalysts
    Li, Zelong
    Qu, Yuanzhi
    Wang, Jijie
    Liu, Hailong
    Li, Mingrun
    Miao, Shu
    Li, Can
    JOULE, 2019, 3 (02) : 570 - 583
  • [6] Direct and Highly Selective Conversion of Synthesis Gas into Lower Olefins: Design of a Bifunctional Catalyst Combining Methanol Synthesis and Carbon-Carbon Coupling
    Cheng, Kang
    Gu, Bang
    Liu, Xiaoliang
    Kang, Jincan
    Zhang, Qinghong
    Wang, Ye
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (15) : 4725 - 4728
  • [7] SELECTIVE SYNTHESIS OF LOWER OLEFINS BY CATALYTIC CONVERSION OF METHANOL
    INUI, T
    ARAKI, E
    SEZUME, T
    ISHIHARA, T
    TAKEGAMI, Y
    REACTION KINETICS AND CATALYSIS LETTERS, 1981, 18 (1-2): : 1 - 5
  • [8] Conversion of carbon dioxide and olefins into cyclic carbonates in water
    Eghbali, Nicolas
    Li, Chao-Jun
    GREEN CHEMISTRY, 2007, 9 (03) : 213 - 215
  • [9] Highly Selective Conversion of Carbon Dioxide to Methane by Copper Single Atom Electrocatalysts
    Liu, Yixian
    Zhang, Mengling
    Bao, Kaili
    Huang, Hui
    Kang, Zhenhui
    CHEMSUSCHEM, 2025, 18 (03)
  • [10] Selective conversion of carbon dioxide into heavy olefins over Ga modified delafossite-CuFeO2
    Chen, Chide
    Wu, Xiaoting
    Zhang, Shuxian
    Qing, Ming
    La, Mengying
    Li, Jifan
    Liu, Chun-Ling
    Dong, Wen-Sheng
    CHEMICAL COMMUNICATIONS, 2023, 59 (82) : 12286 - 12289