Synthesis and crystal structure of a polymeric 1,2,4,5-benzenetetracarboxylato complex of Cu(II) with imidazole, Cu2(C10H2O8)(C3H4N2)6(H2O)4 • 4H2O

被引：20
|
作者：
Cheng, DP
Feng, CJ
Hu, ML
Zheng, YQ
Xu, DJ
Xu, YZ
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[3] Ningbo Univ, Dept Chem, Ningbo 315211, Peoples R China
[4] Wenzhou Normal Coll, Dept Chem, Wenzhou, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 52卷 / 03期
基金：
中国国家自然科学基金;
关键词：
copper(II); crystal structure; polymeric; 1,2,4,5-benzenetetracarboxyl acid; imidazole;
D O I：
10.1080/00958970108022590
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex, Cu-2(C10H2O8)(C3H4N2)(6)(H2O)(4) . 4H(2)O, consists of polymeric copper(II) complex anions and discrete copper(II) complex cations. Benzenetetracarboxyl anions bridge copper(II) atoms coordinated to water and imidazole groups to form the anionic polymeric chains along the a axis, while discrete copper(II) complex cations involving four imidazole and two water ligands are packed between parallel polymeric anionic chains, an extensive H-bonding network linking complex cations and anions.
引用
收藏
页码：245 / 251
页数：7
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