We measured phosphorus (P) chemical pools of genetic horizons of five representative pedons from central southern Cameroon. Our objectives were to assess the relative abundance of P pools and to empirically model their interrelations and contributions to a P availability index. The fractionation scheme followed a modified Hedley sequential procedure with anion exchange resin, 0.5 M sodium bicarbonate (NaHCO3; Pi and Po), 0.1 M sodium hydroxide (NaOH; Pi and Po), 0.5 M hydrochloric acid (HCl; Pi), and 2 M sulfuric acid (H2SO4) after soil ignition at 550 oC. Resin P, sodium bicarbonate (NaHCO3-P; Pi and Po), and HCl-Pi-extractable pools accounted for 1.0, 5.7 and 0.7 % of total P (TP) respectively. The NaOH-P and residual P pools measured through 2 M H2SO4 emerged as the largest and most variable pools, accounting for 86.2% of TP. The relative abundance of extracted P pools decreased in the order resin P NaHCO3-P HCl-P NaOH-P H2SO4-P. Bray 1 P was significantly correlated with all P pools except NaHCO3-Pi, NaOH-Pi, and residual pools.