Preparation of silyl substituted crotylzinc reagents and their highly diastereoselective addition to carbonyl compounds

被引：21
|
作者：
Helm, Matthew D. [1 ]
Mayer, Peter [1 ]
Knochel, Paul [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 16期
关键词：
D O I：
10.1039/b802157k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Readily prepared beta-silyl substituted crotylzinc reagents undergo highly selective allylation of carbonyl compounds leading to syn-homoallylic alcohols.
引用
收藏
页码：1916 / 1917
页数：2
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