Photolysis of matrix-isolated 1,3,4,6-tetrathiapentalene-2,5-dione

被引：0

作者：

Risi, F ^{[1
]}

Aycard, JP ^{[1
]}

机构：

[1] Univ Aix Marseille 1, CNRS, UMR 6633, Equipe Spectrometries & Dynam Mol, F-13397 Marseille 20, France

来源：

SPECTROSCOPY LETTERS | 2001年 / 34卷 / 02期

关键词：

1,3,4,6-tetrathiapentalene-2,5-dione; photolysis; cryogenic matrix; laser UV irradiation; FT-IR spectroscopy; kinetic;

D O I：

10.1081/SL-100002006

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Laser UV irradiation at 300 nm of 1,3,4,6-tetrathiapentalene-2,5-dione 1 isolated in argon matrix at 1 OK yields CO, CS2 and SCO by two competitive pathways. The reaction was monitored by FTIR spectroscopy. The reaction products were assigned by comparison of their infrared spectrum with those obtained from literature data and the ab initio RHF/DZP calculated spectrum for 1 was perform. The kinetic data shows similar rate constant for the two processes (about 5 10(-2) min(-1)). Irradiation of carbonyl sulfide at 260 nm yields carbon monoxide and S atoms which react with carbon atoms trapped in the same matrix cage to yield CS2.

引用

页码：167 / 177

页数：11

共 50 条

[1] 1,3,4,6-Tetrathiapentalene-2,5-dione
Muller, Harald
Averbuch, Marie-Therese
[J]. Acta Crystallographica Section C: Crystal Structure Communications, 1999, 55 (04): : 590 - 592
[2] 1,3,4,6-tetrathiapentalene-2,5-dione
Müller, H
Averbuch, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 590 - 592
[3] Study on the synthesis of 1,3,4,6-tetrathiapentalene-2,5-dione(thiapendione)
Liu, SG
Wu, PJ
Liu, YQ
Zhu, DB
[J]. CHINESE CHEMICAL LETTERS, 1995, 6 (05) : 363 - 366
[4] STUDY ON THE SYNTHESIS OF 1,3,4,6-TETRATHIAPENTALENE-2,5-DIONE(THIAPENDIONE)
Sheng Gao LIU
Pei Ji WU
Yun Qi LIU
and Dao Ben ZHU (Institute of Chemistry
[J]. Chinese Chemical Letters, 1995, (05) : 363 - 366
[5] THIAPEN CHEMISTRY .2. SYNTHESIS OF 1,3,4,6-TETRATHIAPENTALENE-2,5-DIONE
SCHUMAKER, RR
ENGLER, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (16) : 5521 - 5522
[6] UNEXPECTED MONONUCLEAR METAL-COMPLEXES DERIVED FROM 1,3,4,6-TETRATHIAPENTALENE-2,5-DIONE
VICENTE, R
RIBAS, J
CASSOUX, P
[J]. NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1984, 8 (11): : 653 - 658
[7] ELECTROCHEMICAL SYNTHESIS OF 1,3,4,6-TETRATHIAPENTALENE-2,5-DITHIONE
KRUG, WP
BLOCH, AN
COWAN, DO
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (18) : 660 - 660
[8] THIAPEN CHEMISTRY .1. SYNTHESIS OF 1,3,4,6-TETRATHIAPENTALENE-2,5-BIS(DIALKYLIMINIUM) SALTS
SCHUMAKER, RR
ENGLER, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (16) : 5519 - 5521
[9] Synthesis of μ-C2S44- cobalt complexes by activation of the 1,3,4,6-tetrathiapentalene-2,5-dione, and electrochemical study of [(Cp*Co)2(μ-C2S4)]
Guyon, F
Jourdain, IV
Knorr, M
Lucas, D
Monzon, T
Mugnier, Y
Avarvari, N
Fourmigué, M
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (08) : 2026 - 2033
[10] Theoretical and experimental vibrational property of 1,3,4,6-tetramethylpiperazine-2,5-dione
Pan, Yingying
Tang, Guodong
Jiang, Yilan
Jiang, Linxia
Zhang, Ju
Lu, Renjing
Culnane, Lance F.
Zhang, Yu
Li, Rongqing
[J]. SPECTROSCOPY LETTERS, 2016, 49 (10) : 647 - 653

← 1 2 3 4 5 →